Chosen Solution

I will install a SSD drive in my optical bay, and a 500 Gb hard drive at 7400 rpm in the primary hard drive bay on my MacBook Core 2 Duo. In the SSD be installing the operating system (Mac OS X), but I need to install Windows XP on a partition on the hard disk but bootcamp does not allow the installation from a USB optical drive, how I can do?

Go to Applications folder > Utilities> Boot Camp Assistant and set it up.